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    陕南地区硫铁矿矿区污染特征及铁离子的演变机制

    Pollution Characteristics And Evolution Mechanism Of Iron Ions In Pyrite Mining Areas In Southern Shaanxi Province

    • 摘要: 硫铁矿及其伴生矿石中含有重金属,低品位废矿石长期在酸性水体浸泡下,废矿渣中的重金属污染物被溶出,形成严重的次生重金属污染。通过对陕南地区硫铁矿矿区污染特征及铁离子的演变机制的研究分析工作,为硫铁矿废弃矿山精准治污、科学治污提供有效支撑。研究结果显示,硫化物矿石表面氧化并不是均一发生的,氧化程度受介质的酸碱度、氧化剂(02和Fe3+)浓度、温度、细菌等因素影响。因此,可通过改变矿石赋存条件以及以废矿渣为主要原料的地质聚合物新材料的运用,浸出重金属含量会大幅度降低,水质酸碱度逐渐改善。

       

      Abstract: Pyrite and its associated ores contain heavy metals.Low grade waste ore is soaked in acidic water for a long time,and heavy metal pollutants in waste slag are dissolved,forming serious secondary heavy metal pollution.By studying and analyzing the pollution characteristics and evolution mechanism of iron ions in pyrite mining areas in southern Shaanxi,effective support is provided for precise and scientific pollution control of abandoned pyrite mines.The research results show that surface oxidation of sulfide ores does not occur uniformly,and the degree of oxidation is influenced by factors such as the acidity and alkalinity of the medium,the concentration of oxidants (02 and Fe3+),temperature,and bacteria.Therefore,by changing the ore occurrence conditions and using new geological polymer materials mainly made from waste slag,the leaching heavy metal content can be significantly reduced,and the acidity and alkalinity of water quality can gradually improve.

       

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